Larger Groups, Smaller Enantioselectivity? Two Anthracene-Containing, Pyridino-Crown Ether-Based Fluorescent Sensor Molecules
نویسندگان
چکیده
(R,R)- and (S,S)-enantiomers of anthracene-containing pyridino-18-crown-6 ether having tert-butyl groups at the stereogenic centers were prepared with aim achieving higher enantioselectivity than for reported (S,S)-analogue isobutyl groups. The enantiomeric recognition abilities new sensor molecules toward chiral protonated primary amines amino acid esters studied in acetonitrile by UV–vis fluorescence spectroscopies. pKa values these pyridino-crown ethers their (S,S)-analogues methyl or have also been determined acetonitrile.
منابع مشابه
Formation of Supramolecular Polymers from Homoditopic Molecules Containing Secondary Ammonium Ion and Crown Ether Moieties
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ژورنال
عنوان ژورنال: Periodica Polytechnica Chemical Engineering
سال: 2022
ISSN: ['1587-3765', '0324-5853']
DOI: https://doi.org/10.3311/ppch.20468