Larger Groups, Smaller Enantioselectivity? Two Anthracene-Containing, Pyridino-Crown Ether-Based Fluorescent Sensor Molecules

نویسندگان

چکیده

(R,R)- and (S,S)-enantiomers of anthracene-containing pyridino-18-crown-6 ether having tert-butyl groups at the stereogenic centers were prepared with aim achieving higher enantioselectivity than for reported (S,S)-analogue isobutyl groups. The enantiomeric recognition abilities new sensor molecules toward chiral protonated primary amines amino acid esters studied in acetonitrile by UV–vis fluorescence spectroscopies. pKa values these pyridino-crown ethers their (S,S)-analogues methyl or have also been determined acetonitrile.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A New Saccharides and Nnucleosides Sensor Based on Tetrathiafulvalene-anthracene Dyad with Two Boronic Acid Groups

A new saccharides sensor based on the TTF-anthracene dyad with two boronic acid (2) groups was designed and synthesized. This new saccharides sensor shows selectivity towards D-glucose while its analogue with one boronic acid group (1) was reported to bind D-Fructose selectively. Moreover, reaction of compound 2 with uridine induced even larger fluorescence enhancement under the same condition.

متن کامل

A new optical/electrochemical Na+ sensor based on platinum(II) complexes containing crown ether annelated dithiolate ligands.

Two new platinum(II) complexes containing both 4,4'-di-tert-butyl-2,2'-bipyridine (dbbpy) and crown ether annelated dithiolate ligands, [Pt(dbbpy)(3O-C2S4)] (, 3O-C2S4(2-)=1,4,7-trioxa-10,13-dithiacyclopentadec-11-ene-11,12-dithiolate) and [Pt(dbbpy)(4O-C2S4)] (, 4O-C2S(4)2-=1,4,7,10-tetraoxa-13,16-dithiacyclooctadec-14-ene-14,15-dithiolate), have been prepared and characterized. These two comp...

متن کامل

Predicting Customer-Expectation-Based Warranty Cost for Smaller-the- Better and Larger-the-Better Performance Characteristics

The quality loss function assumes a fixed target and only accounts for immediate issues within manufacturing facilities whereas warranty loss occurs during customer use. Based on the two independent variables, product performance and consumers’ expectation, a methodology to predict the probability of customer complaint is presented in this paper. The formulation presented will serve as a basic ...

متن کامل

Responsive supramolecular gels constructed by crown ether based molecular recognition.

Responsive supramolecular gels were constructed from crown ether terminated four-arm star poly(epsilon-caprolactone) (PCL-DB24C8) and dibenzylammonium-terminated two-arm PCL-DBAS (see scheme), exploiting the formation of pseudorotaxane linkages between crown ether and ammonium moieties. The resultant supramolecular gels exhibit thermo- and pH-induced reversible gel-sol transition.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Periodica Polytechnica Chemical Engineering

سال: 2022

ISSN: ['1587-3765', '0324-5853']

DOI: https://doi.org/10.3311/ppch.20468